Angelina Jolie and Billy Bob Thorton (Little Church of the West, 2000)
Two months of intense courtship led to marriage for Angelina Jolie and Billy Bob Thorton, who both famously wore vials of each other's blood around their necks. Despite their odd and very public displays of affection, Angelina and Billy ended their marriage three years later. Could it have been their 20-year age difference? Billy Bob doesn't think so.
Of their marriage, Billy Bob told ABC, "We had a great marriage and I chickened out because I didn't feel good enough. That's all that happened. It was no big deal, we never hated each other."