Love on Set: 13 of TV's Hottest Co-Star Couples

These two Gossip Girl co-stars met, dated, and broke up during filming. Jessica Szohr (Vanessa) and Ed Westwick (Chuck) got together in 2008 after getting to know one another as friends, but Jess’s alleged cheating put an end to the PDA-heavy affair in April 2010. They rekindled things briefly in August 2010, but it didn’t stick.

The former twosome is currently single and ready to mingle. Ed had a brief dalliance with Secret Circle actress Phoebe Tonkin (Faye) in early 2011, and Jess enjoyed a rumored fling with Packers QB Aaron Rodgers around the time of the 2011 Super Bowl.