She's All That: Where Are They Now? (PHOTOS)

Dule’s character, Preston, aims to be the voice of reason in Zack and Dean’s hairbrained bet. He doesn’t stop things from happening, but he does befriend Laney in the process. Shortly after She’s All That, Dule starred on a little show called The West Wing as Charlie Young, personal aide to president Josiah Bartlet.

After the hit series ended in 2006, Dule landed another prime TV gig, this time on USA’s buddy crime comedy Psych. He plays Gus, a pharmaceutical salesman who gets dragged into his friend Shawn’s private detective business. The show’s seventh season is set to premiere this February.