Credit: George Pimentel/Getty Images Photo: Nina Dobrev and Joe Jonas Host Free the Children's "We Day" on September 27, 2011 in Toronto, Canada

The ever-chic Nina Dobrev (Elena) took time out of her busy Vampire Diaries-shooting schedule to host Free the Children’s “We Day” with Joe Jonas. The Bulgarian beauty headed to Toronto, Canada — where she grew up — on September 27 to present a variety of performers and activists to 18,000 students.

“Wow!!! We Day rocks, So many amazing kids, such great energy! Thanks for the warm reception everyone..Joe and I are so happy to hang w/ you!” tweeted Nina.

If Nina’s inspired your philanthropic side, “Like” We Day’s Facebook page and for every “Like,” sponsors will donate $1 to Free the Children, an organization that seeks to free children from poverty and empower young people.

“We Day” will air on October 30 at 7/8c and 10/11c, on MuchMusic and will also stream online.