Damon and Elena’s First Dance
While Stefan was a little preoccupied with his, er, hunger, Damon (and his piercing blue eyes) stepped in as Elena’s escort at the Miss Mystic Falls Pageant. And, for the first time, Elena saw another side to Stefan’s older bro. She also had never been that close to his eyes before. Yum.
Season 1, Episode 18, “Miss Mystic Falls”